Fuente: wikipedia
Alexander
Mikhaylovich Zaitsev (Russian: Алекса́ндр Миха́йлович За́йцев), also spelled as
Saytzeff and Saytzev (2 July 1841 – 1 September 1910), was a Russian chemist
from Kazan. He
worked on organic compounds and proposed Zaitsev's rule, which predicts the
product composition of an elimination reaction.
Zaitsev was
the son of a tea and sugar merchant, who had decided that his son should follow
him into the mercantile trades. However, at the urging of his maternal uncle,
the physicist Lyapunov, Zaitsev was allowed to enroll at Kazan' university to study economics. At this
time, Russia
was experimenting with the cameral system, meaning that every student
graduating in law and economics from a Russian university had to take two years
of chemistry. Zaitsev was thus introduced to Aleksandr Mikhailovich Butlerov.
Early on,
Zaitsev began working with Butlerov, who clearly saw in him an excellent
laboratory chemist, and whose later actions showed that he felt that Zaitsev
was an asset to Russian organic chemistry. On the death of his father, Zaitsev
took his diplom in 1862, and immediately went to western Europe to further his
chemical studies, studying with Hermann Kolbe at Marburg, and with Charles
Adolphe Wurtz in Paris.
Between
1862 and 1864, he studied with Kolbe at Marburg,
and here Zaitsev discovered the sulfoxides and trialkylsulfonium salts. In
1864, he moved to Paris, where he worked for a
year in the laboratories of Wurtz before returning to Marburg in 1865.
In order to
teach, he required either a master's degree from a Russian university, or a Ph.
D. from a foreign university, so he wrote up his work on the sulfoxides and
submitted it to the University
of Leipzig where he was
awarded the Ph. D. in 1866.
Zaitsev
submitted his Dr. Chem. dissertation in 1870, and was awarded the degree over
the indirect objections of Markovnikov (as second examiner of the dissertation,
Markovnikov had written an overtly positive assessment that was meant to be
read between the lines). The same year, he was promoted to Ordinary Professor
of Chemistry.
His
research at Kazan
was primarily concerned with the development of organozinc chemistry and the
synthesis of alcohols.
Zaitsev's
Rule was reported in 1875, and appeared just as his nemesis, Markovnikov, (who
had made a prediction which the rule contradicts) was taking the Chair at Moscow University.
Zaitsev received several honors: he was elected as a Corresponding member of
the Russian Academy
of Science, an honorary member of Kiev
University, and he served
two terms as President of the Russian Physical-Chemical Society.
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